Thread: Acid Reigns.
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Old October 4th 07, 12:32 AM posted to sci.geo.earthquakes,alt.talk.weather
Weatherlawyer Weatherlawyer is offline
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Default Acid Reigns.

On Oct 3, 8:50 pm, Nosterill wrote:
On Oct 3, 5:25 pm, wrote:



On Oct 3, 10:46 am, Weatherlawyer wrote:
(portions snipped)


Concentrated sulfuric acid is not a very strong oxidizing agent unless
it is hot.


As you point out, concentrated sulfuric acid is not a good oxidizing
agent. Additionally, concentrated sulfuric acid is the term for the
industrial product, which is 98% H2SO4 in water (18 molar
concentration), far more concentrated than acid rain.


An article in the scientific journal "Water, Air, and Soil
Pollution" (http://www.springerlink.com/content/n47407582x2652j7/)
deals with the corrosion of metals by acid rain. Under conditions of
pH 3.5 with 1% salt present at 35 degrees Celsius, mild steel corroded
at the rate of 735 micrometers (millionths of a meter) per year,
galvanized steel at 330 micrometers/year, stainless steel at 2
micrometers/year, and aluminum at 9 micrometers/year. Since a
micrometer is 0.000039 inch, I don't think that acid rain is going to
dissolve the boat.


An earlier poster mentioned fuming sulfuric acid. This is formed by
dissolving an excess of sulfur trioxide in pure sulfuric acid. There
is no way that this reaction is going to occur under ambient
conditions.


I was that earlier poster and I completely agree with you. I made the
fatal mistake of addressing Weatherlawyer's assertion that "Sulphur
will burn in oxygen to form sulphur dioxide but getting
that to form an acid is rather difficult." I had forgotten that he
would rather turn the laws of nature upside down than concede
anything.


I am not about to go back on this thread and examine what was or
wasn't said. It's all empty rhetoric anyway.

I would like to point out that the burning sulphur, whatever it turned
into, would have to turn a few neat tricks itself to get dissolved to
some sort, any sort, of an acid in the pool in time to make travel
difficult for the cast.

I don't see what needs to be conceded. What is wrong with examining
chemistry? It will have to stand in the absence of any technical data
from the pollution sites mentioned here. Or from other sites that
might turn out to be strongly acid.

The reason for my hesitation to accept any spurious nonsense about
acid rain comes from observing the effects of it. It seems to be a
selective destroyer of trees. Blocks of stricken trees -making grids
of live and dead ones, seem to have been formed from it.

Squares more likely down to the selective weed killers that are or
were applied to forests, particularly to spruce plantations.

Perhaps I misunderstand the results.

I can't see the destruction wrought on fish in mountain lakes
occurring because rain falls from the skies. Less so now that I have
read that this rain seems to fall cleaner than when it formed in the
clouds.

Perhaps I am being precipitate but it seems to me that acid rain is no
more than the usual smoke and mirrors employed by journalists on slow
news days. Journalists that aught to be looking more closely at the
state of things.

But what is a poor thaumaturge supposed to say?